Total issues assay for Brazilian Lapa

Jan. 7, 2019
Lapa assay from Total Oil Trading SA’s website.

Lapa assay from Total Oil Trading SA’s website.

In late 2018, Total Oil Trading SA, the oil and gas trading arm of Total SA, Paris, published an assay dated Oct. 8, 2018, for Lapa crude oil, produced from Lapa field in Block BM-S-9A in the Santos basin presalt, 270 km offshore Sao Paulo, Brazil, in 2,140 m of water.

Stationed at Total SA-operated Lapa field in the Santos basin presalt, the 337.4-m long, 28.8-m high Cidade de Caraguatatuba FPSO can produce 100,000 b/d of oil, store 1.6 million bbl of oil, and compress 5 million cu m/day of gas. Photo from Modec Inc.

Lapa field began production in December 2016 via the 100,000-b/d Cidade de Caraguatatuba floating production, storage, and offloading (FPSO) vessel. Alongside its crude production, the 337.4-m long, 28.8-m high FPSO can store 1.6 million bbl of oil and compress 5 million cu m/day of gas.

In January 2018, Petróleo Brasileiro SA transferred most of its ownership interest in, as well as operatorship of, Lapa field to Total. Alongside Total (35%), Lapa field partners include Royal Dutch Shell PLC unit BG E&P Brasil Ltda. (30%), Repsol Sinopec Brasil SA (25%), and Petrobras (10%).

Whole crude

Density at 15° C., kg/cu m.: 916.9

Gravity, °API: 22.7

Acidity, mg KOH/g: 0.44

Sulfur, wt %: 0.57

Mercaptan sulfur, mg/kg: 36

Viscosity at 10° C., cst: 5,560.0

Viscosity at 50° C., cst: 52.9

Pour point, °C.: 12

Total nitrogen, wt %: 0.56

Reid vapor pressure at 37.8° C., kPa: 13

Sodium chloride, mg/kg: 86.7

Nickel, mg/kg: 24.9

Vanadium, mg/kg: 20.0

Chlorides, mg/kg: 39.5

Propane, wt %: 0.1

iso-Butane, wt %: 0.1

n-Butane, wt %: 0.2

Light naphtha, 15-65° C.

Yield on crude, wt %: 1.2

Yield on crude, vol %: 1.6

Density at 15° C., kg/cu m.: 648

Sulfur, wt %: 0.02

Mercaptan sulfur, mg/kg: 2

Research octane no., clear: 72.8

Motor octane no., clear: 71.1

Naphthenes, vol %: 8.4

Aromatics, vol %: 0.4

Light naphtha, 15-80° C.

Yield on crude, wt %: 1.7

Yield on crude, vol %: 2.3

Density at 15° C., kg/cu m.: 662

Sulfur, wt %: 0.02

Mercaptan sulfur, mg/kg: 4

Research octane no., clear: 70.1

Motor octane no., clear: 68.2

Naphthenes, vol %: 15.8

Aromatics, vol %: 1.2

Heavy naphtha, 80-150° C.

Yield on crude, wt %: 5.2

Yield on crude, vol %: 6.3

Density at 15° C., kg/cu m.: 745

Sulfur, wt %: 0.03

Mercaptan sulfur, mg/kg: 17

Naphthenes, vol %: 43.2

Aromatics, vol %: 5.8

Heavy naphtha, 80-175° C.

Yield on crude, wt %: 7.2

Yield on crude, vol %: 8.8

Density at 15° C., kg/cu m.: 755

Sulfur, wt %: 0.04

Mercaptan sulfur, mg/kg: 18

Naphthenes, vol %: 42.7

Aromatics, vol %: 7.1

Heavy naphtha, 100-150° C.

Yield on crude, wt %: 4.1

Yield on crude, vol %: 5.0

Density at 15° C., kg/cu m.: 752

Sulfur, wt %: 0.04

Mercaptan sulfur, mg/kg: 18

Naphthenes, vol %: 43.6

Aromatics, vol %: 6.2

Kerosine, 150-230° C.

Yield on crude, wt %: 6.9

Yield on crude, vol %: 7.9

Density at 15° C., kg/cu m.: 800

Sulfur, wt %: 0.08

Mercaptan sulfur, mg/kg: 19

Smoke point, mm: 22

Acidity, mg KOH/g: 0.18

Cetane index 1990 (D-4737): 42.1

Freeze point, °C.: -56

Aromatics, vol %: 12.8

Viscosity at 50° C., cst: 1.0

Flash point, °C.: 56.9

Kerosine, 175-230° C.

Yield on crude, wt %: 4.8

Yield on crude, vol %: 5.4

Density at 15° C., kg/cu m.: 809

Sulfur, wt %: 0.09

Mercaptan sulfur, mg/kg: 19

Smoke point, mm: 23

Acidity, mg KOH/g: 0.22

Cetane index 1990 (D-4737): 43.2

Freeze point, °C.: -49

Aromatics, vol %: 13.8

Viscosity at 50° C., cst: 1.1

Flash point, °C.: 71.7

Kerosine, 150-250° C.

Yield on crude, wt %: 10.0

Yield on crude, vol %: 11.3

Density at 15° C., kg/cu m.: 809

Sulfur, wt %: 0.09

Mercaptan sulfur, mg/kg: 19

Smoke point, mm: 22

Acidity, mg KOH/g: 0.23

Cetane index 1990 (D-4737): 44.8

Freeze point, °C.: -48

Aromatics, vol %: 14.4

Viscosity at 50° C., cst: 1.1

Flash point, °C.: 62.0

Gas oil, 175-400° C.

Yield on crude, wt %: 29.7

Yield on crude, vol %: 31.6

Density at 15° C., kg/cu m.: 859

Sulfur, wt %: 0.26

Aniline point, °C.: 67

Cetane index 1990 (D-4737): 48.6

Cloud point, °C.: 2

Cold filter plugging point, °C.: -1

Pour point, °C.: -5

Viscosity at 50° C., cst: 3.2

Viscosity at 100° C., cst: 1.5

UOP K factor: 11.7

Flash point, °C.: 90.5

Gas oil, 230-400° C.

Yield on crude, wt %: 24.9

Yield on crude, vol %: 26.2

Density at 15° C., kg/cu m.: 869

Sulfur, wt %: 0.30

Aniline point, °C.: 69

Cetane index 1990 (D-4737): 50.1

Cloud point, °C.: 3

Cold filter plugging point, °C.: 3

Pour point, °C.: 2

Viscosity at 50° C., cst: 4.2

Viscosity at 100° C., cst: 1.8

UOP K factor: 11.7

Flash point, °C.: 106.3

Gas oil, 230-375° C.

Yield on crude, wt %: 21.6

Yield on crude, vol %: 22.9

Density at 15° C., kg/cu m.: 864

Sulfur, wt %: 0.28

Aniline point, °C.: 68

Cetane index 1990 (D-4737): 50.3

Cloud point, °C.: -1

Cold filter plugging point, °C.: -2

Pour point, °C.: -2

Viscosity at 50° C., cst: 3.6

Viscosity at 100° C., cst: 1.6

UOP K factor: 11.7

Flash point, °C.: 104.6

Vacuum distillate, 375-550° C.

Yield on crude, wt %: 21.7

Yield on crude, vol %: 21.2

Density at 15° C., kg/cu m.: 935

Sulfur, wt %: 0.54

Conradson carbon residue, wt %: 0.3

Aniline point, °C.: 82

Total nitrogen, wt %: 0.33

Basic nitrogen, mg/kg: 952

Pour point, °C.: 38

Viscosity at 100° C., cst: 14.3

Viscosity at 150° C., cst: 5.9

UOP K factor: 11.8

Asphaltenes (C7), wt %: 0.1

Vacuum distillate, 375-565° C.

Yield on crude, wt %: 24.0

Yield on crude, vol %: 23.4

Density at 15° C., kg/cu m.: 937

Sulfur, wt %: 0.56

Conradson carbon residue, wt %: 0.4

Aniline point, °C.: 83

Total nitrogen, wt %: 0.35

Basic nitrogen, mg/kg: 1,020

Pour point, °C.: 39

Viscosity at 100° C., cst: 15.8

Viscosity at 150° C., cst: 6.5

UOP K factor: 11.8

Asphaltenes (C7), wt %: 0.1

Vacuum distillate, 375-580° C.

Yield on crude, wt %: 26.3

Yield on crude, vol %: 25.6

Density at 15° C., kg/cu m.: 940

Sulfur, wt %: 0.57

Conradson carbon residue, wt %: 0.6

Aniline point, °C.: 83

Nickel, mg/kg: 1.0

Vanadium, mg/kg: 1.0

Total nitrogen, wt %: 0.37

Basic nitrogen, mg/kg: 1,100

Pour point, °C.: 40

Viscosity at 100° C., cst: 17.4

Viscosity at 150° C., cst: 7.2

UOP K factor: 11.8

Asphaltenes (C7), wt %: 0.2

Vacuum distillate, 400-580° C.

Yield on crude, wt %: 23.0

Yield on crude, vol %: 22.3

Density at 15° C., kg/cu m.: 944

Sulfur, wt %: 0.60

Conradson carbon residue, wt %: 0.7

Aniline point, °C.: 84

Nickel, mg/kg: 1.0

Vanadium, mg/kg: 1.0

Total nitrogen, wt %: 0.40

Basic nitrogen, mg/kg: 1,200

Pour point, °C.: 42

Viscosity at 100° C., cst: 21.7

Viscosity at 150° C., cst: 8.7

UOP K factor: 11.8

Asphaltenes (C7), wt %: 0.2

Residue, > 375° C.

Yield on crude, wt %: 64.3

Yield on crude, vol %: 60.0

Density at 15° C., kg/cu m.: 981

Sulfur, wt %: 0.78

Conradson carbon residue, wt %: 11.0

Acidity, mg KOH/g: 0.1

Nickel, mg/kg: 39.0

Vanadium, mg/kg: 31.0

Total nitrogen, wt %: 0.86

Pour point, °C.: 42

Viscosity at 100° C., cst: 163

Viscosity at 150° C., cst: 56

Asphaltenes (C7), wt %: 3.7

Residue, > 550° C.

Yield on crude, wt %: 42.6

Yield on crude, vol %: 38.7

Density at 15° C., kg/cu m.: 1,007

Sulfur, wt %: 0.90

Conradson carbon residue, wt %: 16.4

Nickel, mg/kg: 58.0

Vanadium, mg/kg: 47.0

Total nitrogen, wt %: 1.13

Pour point, °C.: 57

Viscosity at 100° C., cst: 1,120

Viscosity at 150° C., cst: 363

Penetration, mm/10: 102

Asphaltenes (C7), wt %: 5.6

Residue, > 565° C.

Yield on crude, wt %: 40.3

Yield on crude, vol %: 36.6

Density at 15° C., kg/cu m.: 1,010

Sulfur, wt %: 0.91

Conradson carbon residue, wt %: 17.3

Nickel, mg/kg: 61.0

Vanadium, mg/kg: 49.0

Total nitrogen, wt %: 1.16

Pour point, °C.: 58

Viscosity at 100° C., cst: 1,420

Viscosity at 150° C., cst: 455

Penetration, mm/10: 88

Asphaltenes (C7), wt %: 5.8

Residue, > 580° C.

Yield on crude, wt %: 38.0

Yield on crude, vol %: 34.4

Density at 15° C., kg/cu m.: 1,013

Sulfur, wt %: 0.92

Conradson carbon residue, wt %: 18.2

Nickel, mg/kg: 65.0

Vanadium, mg/kg: 52.0

Total nitrogen, wt %: 1.20

Pour point, °C.: 59

Viscosity at 100° C., cst: 1,840

Viscosity at 150° C., cst: 579

Penetration, mm/10: 77

Asphaltenes (C7), wt %: 6.2