GUIDE TO WORLD CRUDES: Statoil publishes Norne Blend assay

March 1, 2010
Statoil late last year published an assay of its Norne Blend crude oil.

Statoil late last year published an assay of its Norne Blend crude oil.

Norne lies in a license awarded in 1986 and embraces Blocks 6608/10 and 6608/11 in the Norwegian Sea about 85 km from Heidrun in water depths of 380 m.

Production began from Norne on Nov. 6, 1997.

Statoil developed the field with a production and storage ship tied to subsea templates. Flexible risers carry the well stream to the ship, which rotates on a cylindrical turret moored to the seabed. Risers and umbilicals are also connected to the turret. The ship has a processing plant on deck and storage tanks for stabilized oil (OGJ, Dec. 20. 1993, p. 27).

Gas has been exported from Norne since February 2001. It travels through the Norne gas export pipeline and the Aasgard transport trunkline via Karsto north of Stavanger to continental Europe.

The field is roughly 1,400 km north of pipeline landfall at Dornum, Germany.

The current partnership structure is Petoro AS (54%), Statoil (39.1%), and Eni Norge AS (6.9%).

Legend:

1 ND = not detectable; HPLC = high performance liquid chromatography; DVPE = dry vapor pressure equivalent. 2 Corrected in accordance with EN 228. 3 Calculated density for 525+ fraction. 4 Unable to distinguish between 3-methylheptane and cis-1, 3-dimethylcyclohexane.

Whole crude

Density at 15° C., kg/l.: 0.8615

Specific gravity at 60/60° F.: 0.8619

API gravity at 60/60° F.: 32.7

Dry oil density at 15° C., kg/l.: 0.8613

Sulfur, mass %: 0.208

Total acid number, mg KOH/g: 0.19

Reid vapor pressure, kPa: 23.7

Pour point, °C.: 9

Kin. vis. at 20° C., cst: 14.1

Kin. vis. at 50° C., cst: 5.56

Nitrogen, mg/kg: 390

Hydrogen sulfide, mass %:ND1

Vanadium, mg/kg: 0.3

Nickel, mg/kg: 0.9

Sodium, mg/kg: 12

Salt as NaCl, mg/l.: 37.2

Wax content, mass %: 8.2

Flash point, °C.: <10

Water content, mass %: 0.10

Pentanes to 65° C.

Yield on crude, mass %: 1.35

Yield on crude, vol %: 1.77

Density at 15° C., kg/l.: 0.6518

Specific gravity at 60/60° F.: 0.6518

API gravity at 60/60° F.: 85.6

Mercaptan sulfur, mg/kg: <3

n-Paraffins, mass %: 44.8

i-Paraffins, mass %: 41.9

Naphthenes, mass %: 9.6

Aromatics (incl. benzene), mass %: 3.8

n-Paraffins, vol %: 46.4

i-Paraffins, vol %: 42.6

Naphthenes, vol %: 8.2

Aromatics (incl. benzene), vol %: 2.8

Vapor pressure (DVPE), kPa: 122.3

Research octane no.: 78.0

Motor octane no.: 76.1

Research octane no.: 277.8

Motor octane no.: 275.9

65-90° C.

Yield on crude, mass %: 1.75

Yield on crude, vol %: 2.04

Density at 15° C., kg/l.: 0.7352

Specific gravity at 60/60° F.: 0.7354

API gravity at 60/60° F.: 60.9

Sulfur, mass %: <0.001

Mercaptan sulfur, mg/kg: <3

n-Paraffins, mass %: 20.4

i-Paraffins, mass %: 21.6

Naphthenes, mass %: 44.6

Aromatics (incl. benzene), mass %: 13.5

Benzene, mass %: 10.3

n-Paraffins, vol %: 22.6

i-Paraffins, vol %: 23.5

Naphthenes, vol %: 42.7

Aromatics (incl. benzene), vol %: 11.2

Benzene, vol %: 8.6

Vapor pressure (DVPE), kPa: 36.1

Research octane no.: 72.7

Motor octane no.:70.8

Research octane no.: 272.5

Motor octane no.: 270.6

Nitrogen, mg/kg: <1

90-150° C.

Yield on crude, mass %: 8.3

Yield on crude, vol %: 9.1

Density at 15° C., kg/l.: 0.7799

Specific gravity at 60/60° F.: 0.7802

API gravity at 60/60° F.: 49.9

Sulfur, mass %: 0.001

Mercaptan sulfur, mg/kg: <3

n-Paraffins, mass %: 14.5

i-Paraffins, mass %: 14.7

Naphthenes, mass %: 37.1

Aromatics (incl. benzene), mass %: 33.8

Benzene, mass %: 0.9

n-Paraffins, vol %: 16.2

i-Paraffins, vol %: 16.1

Naphthenes, vol %: 37.4

Aromatics (incl. benzene), vol %: 30.3

Benzene, vol %: 0.8

Flash point, °C.: <10

Nitrogen, mg/kg: <1

150-180° C.

Yield on crude, mass %: 3.74

Yield on crude, vol %: 4.04

Density at 15° C., kg/l.: 0.7989

Specific gravity at 60/60° F.: 0.7992

API gravity at 60/60° F.: 45.6

Sulfur, mass %: 0.013

Mercaptan sulfur, mg/kg: <3

Copper corrosion: 1a

Total acid no., mg KOH/g: <0.01

n-Paraffins, mass %: 18.4

i-Paraffins, mass %: 18.6

Naphthenes, mass %: 29.3

Aromatics, mass %: 33.7

n-Paraffins, vol %: 20.2

i-Paraffins, vol %: 19.8

Naphthenes, vol %: 29.0

Aromatics, vol %: 30.9

Aromatics (HPLC)

Total, mass %: 31.0

Monoaromatics, mass %: 30.8

Diaromatics, mass %: 0.2

Polycyclic aromatics, mass %: <0.1

Naphthalenes, vol %: 0.07

Aniline point, °C.: 37.5

Smoke point, mm: 19.0

Flash point, °C.: 35.0

Freezing point, °C.: <–60

Cetane index (D-976): 24.7

Calculated cetane index (D-4737): 29.1

Kin. vis. at 20° C., cst: 1.06

Kin. vis. at 50° C., cst: 0.75

Nitrogen, mg/kg: <1

Distillation D-86 (50%), °C.: 160.5

180-240° C.

Yield on crude, mass %: 9.01

Yield on crude, vol %: 9.43

Density at 15° C., kg/l.: 0.8234

Specific gravity at 60/60° F.: 0.8237

API gravity at 60/60° F.: 40.3

Sulfur, mass %: 0.021

Mercaptan sulfur, mg/kg: <3

Copper corrosion: 1a

Total acid no., mg KOH/g: 0.01

Aromatics (HPLC)

Total, mass %: 25.4

Monoaromatics, mass %: 19.1

Diaromatics, mass %: 6.3

Polycyclic aromatics, mass %: <0.1

Naphthalenes, vol %: 4.02

Aniline point, °C.: 53.9

Smoke point, mm: 19.0

Freezing point, °C.: –48.0

Cloud point, °C.: <–49

Cold-filter plugging point, °C.: <–48

Pour point, °C.: <–48

Cetane no.: 44.8

Cetane index (D-976): 38.5

Calculated cetane index (D-4737): 38.6

Kin. vis. at 20° C., cst: 1.92

Kin. vis. at 50° C., cst: 1.21

Nitrogen, mg/kg: <1

Distillation D-86 (50%), °C.: 207.4

240-320° C.

Yield on crude, mass %: 20.67

Yield on crude, vol %: 20.75

Density at 15° C., kg/l.: 0.8581

Specific gravity at 60/60° F.: 0.8585

API gravity at 60/60° F.: 33.3

Sulfur, mass %: 0.091

Total acid no., mg KOH/g: 0.10

Aromatics (HPLC)

Total, mass %: 29.7

Monoaromatics, mass %: 16.6

Diaromatics, mass %: 12.8

Polycyclic aromatics, mass %: 0.3

Aniline point, °C.: 65.0

Cloud point, °C.: –15

Cold-filter plugging point, °C.: –18

Pour point, °C.: –15

Cetane no.: 50.7

Cetane index (D-976): 46.2

Calculated cetane index (D-4737): 48.3

Kin. vis. at 20° C., cst: 5.35

Kin. vis. at 50° C., cst: 2.63

Nitrogen, mg/kg: 8

Basic nitrogen, mass %: <0.001

Distillation D-86 (50%), °C.: 274.4

Statoil developed Norne with a production and storage vessel that passesses a processing plant on deck and storage tanks for stabilized oil (photo from Statoil).

320-375° C.

Yield on crude, mass %: 13.51

Yield on crude, vol %: 13.34

Density at 15° C., kg/l.: 0.8725

Specific gravity at 60/60° F.: 0.8729

API gravity at 60/60° F.: 30.6

Sulfur, mass %: 0.236

Total acid no., mg KOH/g: 0.18

Aromatics (HPLC)

Total, mass %: 27.5

Monoaromatics, mass %: 16.3

Diaromatics, mass %: 8.3

Polycyclic aromatics, mass %: 2.9

Aniline point, °C.: 78.8

Watson K-factor: 11.8

Cloud point, °C.: 12

Cold-filter plugging point, °C.: 12

Pour point, °C.: 12

Cetane no.: 58.4

Cetane index (D-976): 50.4

Calculated cetane index (D-4737): 61.8

Carbon residue (micromethod), mass %: <0.10

Kin. vis. at 20° C., cst: 17.3

Kin. vis. at 50° C., cst: 6.40

Kin. vis. at 100° C., cst: 2.35

Nitrogen, mg/kg: 86

Basic nitrogen, mass %: 0.004

Refractive index at 67° C.: 1.468

Distillation D-86 (50%), °C.: 335.7

375-420° C.

Yield on crude, mass %: 11.03

Yield on crude, vol %: 10.72

Density at 15° C., kg/l.: 0.8861

Specific gravity at 60/60° F.: 0.8866

API gravity at 60/60° F.: 28.1

Sulfur, mass %: 0.243

Total acid no., mg KOH/g: 0.20

Aniline point, °C.: 91.1

Watson K-factor: 12.0

Pour point, °C.: 30

Carbon residue (micromethod), mass %: <0.10

Kin. vis. at 50° C., cst: 16.1

Kin. vis. at 100° C., cst: 4.81

Vanadium, mg/kg: <0.1

Nickel, mg/kg: <0.1

Nitrogen, mg/kg: 240

Basic nitrogen, mass %: 0.010

Refractive index at 67° C.: 1.473

420-525° C.

Yield on crude, mass %: 18.74

Yield on crude, vol %: 17.91

Density at 15° C., kg/l.: 0.9016

Specific gravity at 60/60° F.: 0.9021

API gravity at 60/60° F.: 25.4

Sulfur, mass %: 0.293

Total acid no., mg KOH/g: 0.20

Aniline point, °C.: 97.2

Watson K-factor: 12.0

Pour point, °C.: 42

Carbon residue (micromethod), mass %: <0.10

Kin. vis. at 50° C., cst: 45.7

Kin. vis. at 100° C., cst: 8.79

Vanadium, mg/kg: <0.1

Nickel, mg/kg: <0.1

Nitrogen, mg/kg: 540

Basic nitrogen, mass %: 0.019

Refractive index at 67° C.: 1.483

375°+ C.

Yield on crude, mass %: 41.12

Yield on crude, vol %: 38.82

Density at 15° C., kg/l.: 0.9128

Specific gravity at 60/60° F.: 0.9133

API gravity at 60/60° F.: 23.4

Sulfur, mass %: 0.359

Total acid no., mg KOH/g: 1.17

Aniline point, °C.: 96.0

Watson K-factor: 12.0

Pour point, °C.: 45

Carbon residue (micromethod), mass %: 2.55

Asphaltenes, mass %: <0.5

n-Pentane insolubles, mass %: 1.1

Ash, mass %: 0.010

Kin. vis. at 50° C., cst: 78.0

Kin. vis. at 100° C., cst: 12.3

Vanadium, mg/kg: 0.7

Nickel, mg/kg: 2.2

Nitrogen, mg/kg: 1,000

Basic nitrogen, mass %: 0.033

Refractive index at 67° C.: 1.492

525°+ C.

Yield on crude, mass %: 11.35

Yield on crude, vol %: 10.19

Density at 15° C., kg/l.: 30.9600

Specific gravity at 60/60° F.: 0.9606

API gravity at 60/60° F.: 15.8

Sulfur, mass %: 0.584

Aniline point, °C.: 99.9

Watson K-factor: 11.8

Pour point, °C.: 51

Carbon residue (micromethod), mass %: 9.61

Asphaltenes, mass %: <0.50

n-Pentane insolubles, mass %: 4.2

Ash, mass %: 0.024

Kin. vis. at 100° C., cst: 122

Kin. vis. at 135° C., cst: 34.4

Vanadium, mg/kg: 2.4

Nickel, mg/kg: 7.9

Nitrogen, mg/kg: 2,390

Basic nitrogen, mass %: 0.072

Penetration at 25° C., mm: 290

Composition, mass %

Normal paraffins

Methane: <0.01

Ethane: 0.02

Propane: 0.16

Butane: 0.31

Pentane: 0.36

Hexane: 0.42

Heptane: 0.50

Octane: 0.58

Nonane: 0.55

Total n-paraffins: 2.91

C4 hydrocarbons

i-Butane: 0.11

C5 hydrocarbons

Isoparaffins

2,2-Dimethylpropane: <0.01

i-Pentane: 0.29

Total C5 i-paraffins: 0.29

Naphthenes

Cyclopentane: 0.05

C6 hydrocarbons

Isoparaffins

2,2-Dimethylbutane: 0.02

2,3-Dimethylbutane: 0.05

2-Methylpentane: 0.22

3-Methylpentane: 0.14

Total C6 i-paraffins: 0.43

Naphthenes

Methylcyclopentane (incl. 2,2-Dimethylpentane): 0.34

Cyclohexane: 0.60

Total C6 naphthenes: 0.94

Aromatics

Benzene: 0.34

C7 hydrocarbons

Isoparaffins

2,2,3-Trimethylbutane: <0.01

3,3-Dimethylpentane: <0.01

2,4-Dimethylpentane: 0.02

2-Methylhexane: 0.17

2,3-Dimethylpentane: 0.03

3-Methylhexane: 0.16

Total C7 i-paraffins: 0.40

Naphthenes

cis-1,3-Dimethylcyclopentane: 0.08

trans-1,3-Dimethylcyclopentane: 0.07

trans-1,2-Dimethylcyclopentane: 0.13

Methylcyclohexane: 1.28

Ethylcyclopentane: 0.06

1,1-Dimethylcyclopentane: 0.04

Total C7 naphthenes: 1.65

Aromatics

Toluene: 1.40

C8 hydrocarbons

Isoparaffins

2,2,4-Trimethylpentane: <0.01

2,5-Dimethylhexane: 0.02

2,4-Dimethylhexane: 0.03

3,4-Dimethylhexane: <0.01

3,3-Dimethylhexane: <0.01

2,3-Dimethylhexane (incl. naphthenic compound): 0.04

2-Methyl-3-ethylpentane: <0.01

2-Methylheptane: 0.17

4-Methylheptane: 0.06

3-Methylheptane: <0.01

2,3,4-Trimethylpentane: <0.01

Total C8 i-paraffins: 0.32

Naphthenes

1,1,3-Trimethylcyclopentane (incl. 2,2-Dimethylhexane): 0.04

trans, cis-1,2,4-Trimethylcyclopentane: 0.03

trans,cis-1,2,3-Trimethylcyclopentane: 0.03

trans-1,4-Dimethylcyclohexane: 0.10

1,1-Dimethylcyclohexane: 0.04

trans-1-Methyl-3-ethylcyclopentane: 0.02

cis-1-Methyl-3-ethylcyclopentane: 0.02

trans-1-Methyl-2-ethylcyclopentane: 0.03

trans-1,2-Dimethylcyclohexane: 0.11

2-Propylcyclopentane: <0.01

cis-1,2-Dimethylcyclohexane: 0.05

Ethylcyclohexane: 0.26

1-Propylcyclopentane: 0.06

cis,cis-1,2,4-Trimethylcyclopentane: <0.01

1-Methyl-1-ethylcyclopentane: <0.01

cis-1,3-Dimethylcyclohexane (incl. naphthenic compound): 40.37

Total C8 naphthenes: 1.16

Aromatics

Ethylbenzene: 0.21

m-Dimethylbenzene (m-xylene): 0.89

p-Dimethylbenzene (p-xylene): 0.27

o-Dimethylbenzene (o-Xylene): 0.32

Total C8 aromatics: 1.69

C9 hydrocarbons

Isoparaffins

3,5-Dimethylheptane: 0.06

4-Methyloctane: 0.06

2-Methyloctane: 0.09

3-Methyloctane: 0.11

2,3,4-Trimethylhexane: <0.01

Unidentified paraffin: 0.03

Total C9 i-paraffins: 0.36

Naphthenes

1,1,3-Trimethylcyclohexane: 0.06

1-Methyl-2-propylcyclopentane: 0.03

1-Methyl-3-ethylcyclohexane: 0.09

1-Methyl-4-ethylcyclohexane: 0.06

1,1,4-Trimethylcyclohexane: 0.04

Unidentified naphthenes: 0.04

Total C9 naphthenes: 0.33

Total identified: 12.37
Total unidentified: 0.10

Total C10+: 87.54

More Oil & Gas Journal Current Issue Articles
More Oil & Gas Journal Archives Issue Articles
View Oil and Gas Articles on PennEnergy.com